Safety data sheet EXTRA-SRENGTH

Trade name: Extra-Strength Cleaner

1 Identification of the substance/mixture and of the company/undertaking

Product dilution information: 3.5g per 1 quart of warm water

2 Hazards identification

• 2.1 Classification of the substance or mixture

• Classification according to Regulation (EC) No 1272/2008

Product as SOLD 

Product at USE DILUTION

GHS05 

Eye Dam. 1 H318 Causes serious eye damage.

Not classified. 

Not classified.

GHS07 

Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation.

Not classified. 

Not classified.

• Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xn; Harmful 

R22: Harmful if swallowed.

Not classified.

Xi; Irritant 

R36: Irritating to eyes

Not classified.

• Information concerning particular hazards for human and environment:

The product has to be labelled due to the calculation  procedure of the “General Classification guideline for  preparations of the EU” in the latest valid version.

The mixture does not meet the criteria for classification.

Trade name: Extra-Strength Cleaner

• Classification system:

The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

The classification is in accordance with the latest editions of international substances lists, and is supplemented by  information from technical literature and by information provided by the company.

• 2.2 Label elements

• Labeling according to Regulation (EC) No 1272/2008

Product as SOLD 

Product at USE DILUTION

The product is classified and labeled according to the CLP  regulation.

The mixture does not meet the criteria for classification.

• Hazard pictograms

GHS05 GHS07

None

• Signal word Danger 

No signal word.

• Hazard-determining components of labelling:

sodium dodecylbenzenesulphonate 

alcohols, C12-15, ethoxylated

Not applicable

• Hazard statements

The following Hazard Statements are applicable only to the  EU regulations and not the US GHS regulation: H412. H302 Harmful if swallowed. 

H315 Causes skin irritation. 

H318 Causes serious eye damage.

• Precautionary statements

Trade name: Extra-Strength Cleaner

3 Composition/information on ingredients

• Dangerous components:

CAS: 25155-30-0 

EINECS: 246-680-4

sodium dodecylbenzenesulphonate 

Xn R22; Xi R36

10-25%

Acute Tox. 4, H302; Eye Irrit. 2A, H319

CAS: 497-19-8 

EINECS: 207-838-8 

Index number: 011-005-00-2

Sodium Carbonate 

Xi R36

10-25%

Eye Irrit. 2A, H319

CAS: 68131-39-5 

alcohols, C12-15, ethoxylated 

Xi R41

<10%

Eye Dam. 1, H318

CAS: 63231-67-4 

Amorphous Silicon Dioxide 

<10%

4 First-aid measures

• 4.1 Description of first aid measures

Product as SOLD 

Product at USE DILUTION

• General information: No special measures required. 

No special measures required. 

• After inhalation: Supply fresh air; consult doctor in case of  complaints.

No special measures required. Treat symptomatically.

• After skin contact: 

Brush off loose particles from skin. 

Immediately rinse with water. 

If skin irritation continues, consult a doctor.

No known effect after skin contact. Rinse with water for a  few minutes.

• After eye contact: 

Remove contact lenses if worn. 

Rinse opened eye for several minutes under running water.  If symptoms persist, consult a doctor.

No known effect after eye contact. Rinse with water for a  few minutes. If irritation persists, get medical attention.

• After swallowing:  

Rinse out mouth and then drink plenty of water. 

Do not induce vomiting; call for medical help immediately.

Get medical attention if symptoms occur.

• 4.2 Most important symptoms and effects, both acute  and delayed  

Eye damage. 

Irritant to skin and mucous membranes. 

Gastric or intestinal disorders.

No known effects.

• Hazards Danger of severe eye injury. Harmful if swallowed. 

No known effects.

• 4.3 Indication of any immediate medical attention and special treatment needed

No further relevant information available. 

No further relevant information available.

Trade name: Extra-Strength Cleaner

5 Fire-fighting measures

6 Accidental release measures

• 6.1 Personal precautions, protective equipment and emergency procedures

Product as SOLD 

Product at USE DILUTION

Use respiratory protective device against the effects of  fumes/dust/aerosol. 

Wear protective equipment. Keep unprotected persons  away. 

Ensure adequate ventilation 

Avoid formation of dust. 

Product forms slippery surface when combined with water.

Use personal protective equipment as required.

• 6.2 Environmental precautions: 

No special measures required. 

Avoid contact of large amounts of spilled material and run off  with soil and surface waterways.

• 6.3 Methods and material for containment and cleaning up:

Pick up mechanically. 

Dispose contaminated material as waste according to  item 13. 

Clean the affected area carefully; suitable cleaners are: Warm water

Large Spills: Flush area with water. Prevent entry into water ways. 

Small Spills: Wipe up with absorbent material.

• 6.4 Reference to other sections

See Section 7 for information on safe handling. 

See Section 8 for information on personal protection  equipment. 

See Section 13 for disposal information.

See Section 7 for information on safe handling. 

See Section 8 for information on personal protection equip ment. 

See Section 13 for disposal information.

7 Handling and storage

• 7.1 Precautions for safe handling

Product as SOLD 

Product at USE DILUTION

Prevent formation of dust. 

Any unavoidable deposit of dust must be regularly  removed.

No special measures required.

• Information about fire - and explosion protection: 

Dust can combine with air to form an explosive mixture. 

No special measures required.

Trade name: Extra-Strength Cleaner

Product as SOLD 

Product at USE DILUTION

• 7.2 Conditions for safe storage, including any incompatibilities

• Storage:

• Requirements to be met by storerooms and receptacles:

Protect from humidity and water. 

Avoid storage near extreme heat, ignition sources or open  flame.

Keep out of reach of children.

• Information about storage in one common storage facility:

Store away from foodstuffs. 

Store away from oxidizing agents. 

Do not store together with acids.

No storage precautions necessary.

• Further information about storage conditions: 

Store in cool, dry conditions in well sealed receptacles. This product is hygroscopic. 

Protect from humidity and water. 

Protect from freezing.

No storage precautions necessary.

• 7.3 Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

• Additional information about design of technical facilities: No further data; see item 7.

Product as SOLD 

Product at USE DILUTION

• 8.1 Control parameters

• Ingredients with limit values that require monitoring at the workplace:

112926-00-8 Precipitated silica (Silica-Amorphous) 

PEL (USA) 20mppcf or 80mg/m3 /%SiO2 

REL (USA) Long-term value: 6 mg/m³ 

See Pocket Guide App. C 

TLV (USA) TLV withdrawn 

EL (Canada) Long-term value: 4* 1,5** mg/m³ 

*total; **respirable 

EV (Canada) Long-term value: 10 mg/m³ 

• DNELs No further relevant information available. 

• PNECs No further relevant information available. 

• Additional information: The lists valid during the making were used as basis.

• 8.2 Exposure controls

• Personal protective equipment:

• General protective and hygienic measures: 

The usual precautionary measures are to be adhered to  when handling chemicals. 

Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. 

Avoid close or long term contact with the skin.

Not required under normal conditions of use.

Trade name: Extra-Strength Cleaner

Product as SOLD 

Product at USE DILUTION

• Respiratory protection: 

Not required under normal conditions of use. 

For spills, respiratory protection may be advisable. Use suitable respiratory protective device when high con centrations are present. 

Particulate mask should filter at least 99% of airborne  particles.

A respirator is not required under normal and intended  conditions of use.

• Protection of hands: 

Protective gloves 

The glove material has to be impermeable and resistant to  the product/ the substance/ the preparation.  

Selection of the glove material on consideration of the  penetration times, rates of diffusion and the degradation.

No protective equipment is needed under normal  conditions.

• Material of gloves

The selection of the suitable gloves does not only depend  on the material, but also on further marks of quality and  varies from manufacturer to manufacturer. As the product is  a preparation of several substances, the resistance of the  glove material can not be calculated in advance and has  therefore to be checked prior to the application.

No protective equipment is needed under normal  conditions.

• Penetration time of glove material

The exact break through time has to be found out by the  manufacturer of the protective gloves and has to 

be observed.

No protective equipment is needed under normal  conditions.

• Eye protection: 

Safety glasses

No protective equipment is needed under normal  conditions.

• Body protection: 

Alkaline resistant protective clothing 

No protective equipment is needed under normal  conditions.

• Limitation and supervision of exposure into the environment

No further relevant information available. 

No further relevant information available.

• Risk management measures

See Section 7 for additional information. 

No further relevant information available.

See Section 7 for additional information. 

No further relevant information available.

9 Physical and chemical properties

Product as SOLD 

Product at USE DILUTION

• 9.1 Information on basic physical and chemical properties

• General Information 

• Appearance: 

 Form:  

Powder 

 Color: 

Green

Liquid 

Green

Trade name: Extra-Strength Cleaner

Product as SOLD 

Product at USE DILUTION

• General Information 

• Appearance: 

 Form:  

Powder 

 Color: 

Green 

• Odor:  

Pleasant 

• Odor threshold:  

Not determined.

Liquid 

Green 

Pleasant 

Not determined.

• pH-value at 20 °C: Not applicable. 

9.5 ± 0.5

• Change in condition 

 Melting point/Melting range:  

Undetermined. 

 Boiling point/Boiling range:  

Undetermined.

Not applicable. 

212 °F / 100 °C

• Flash point: >200 °F / >93.3 °C 

Not determined.

• Flammability (solid, gaseous): Not determined. 

Not applicable.

• Ignition temperature: Not determined. 

Not applicable.

• Decomposition temperature: Not determined. 

Not determined.

• Self-igniting: Product is not self-igniting. 

Product is not self-igniting.

• Danger of explosion: Product does not present an  explosion hazard.

Product does not present an explosion  hazard.

• Explosion limits: 

 Lower: 

Not determined. 

 Upper: 

Not determined.

Not determined. 

Not determined.

• Vapor pressure at 20 °C: Not applicable. 

Not determined.

• Density at 20 °C:  

1.1 g/cm³ 

• Relative density  

Not determined. 

• Vapor density  

Not applicable. 

• Evaporation rate 

Not applicable.

1.00 g/cm³ 

Not determined. 

Not applicable. 

Not applicable

• Solubility in / Miscibility with water: Soluble. 

Complete

• Partition coefficient  

 (n-octanol/water): Not determined. 

Not determined.

• Viscosity: 

 Dynamic: 

Not applicable. 

 Kinematic:  

Not applicable.

Not determined. 

Not determined.

• 9.2 Other information No further relevant information  available.

No further relevant information available.

10 Stability and reactivity

Trade name: Extra-Strength Cleaner

11 Toxicological information

• 11.1 Information on toxicological effects

Product as SOLD 

Product at USE DILUTION

• Acute toxicity: Calculated oral toxicity LD50: 2,686 mg/kg  (Rat)

Non-toxic at use-dilution.

• Primary irritant effect:

• on the skin: Slight irritant effect on skin and mucous  membranes. 

• on the eye: Irritating effect. 

No adverse effects due to skin contact are expected. Direct contact with eyes may cause temporary irritation.

• Sensitization: No sensitizing effects known. 

No sensitizing effects known.

• Additional toxicological information:

The product shows the following dangers according to the calculation method of the General EU 

Classification Guidelines for Preparations as issued in the latest version:

Harmful 

Irritant

Not classified 

No known significant effects or critical hazards.

12 Ecological information

Trade name: Extra-Strength Cleaner

13 Disposal considerations

• 13.1 Waste treatment methods

Product as SOLD 

Product at USE DILUTION

• Recommendation

Small amounts may be diluted with plenty of water and  washed away. Dispose of bigger amounts in 

accordance with Local Authority requirements. 

The user of this material has the responsibility to dispose of  unused material, residues and containers in 

compliance with all relevant local, state and federal laws and  regulations regarding treatment, storage and 

disposal for hazardous and nonhazardous wastes. Residual  materials should be treated as hazardous.

Diluted product can be flushed to sanitary sewer. Discard  empty container in trash.

• Uncleaned packaging:

• Recommendation: Disposal must be made according to  official regulations. 

• Recommended cleansing agents: Water only.

Diluted product can be flushed to sanitary sewer. Discard  empty container in trash.

14 Transport information

Product as SOLD

• 14.1 UN-Number 

• DOT, ADR, ADN, IMDG, IATA N/A

• 14.2 UN proper shipping name 

• DOT, ADR, ADN, IMDG, IATA Cleaning Compounds, NOI, powder.

• 14.3 Transport hazard class(es) 

• DOT, ADR, ADN, IMDG, IATA 

• Class N/A

• 14.4 Packing group 

• DOT, ADR, IMDG, IATA N/A

• 14.5 Environmental hazards: 

• Marine pollutant: No

• 14.6 Special precautions for user Not applicable.

• 14.7 Transport in bulk according to Annex II of  

 MARPOL73/78 and the IBC Code Not applicable.

• UN “Model Regulation”: Cleaning Compounds, NOI, powder.

Product at USE DILUTION Not intended for transport.

15 Regulatory information

Product as SOLD 

Product at USE DILUTION

• Section 355 (extremely hazardous substances):

None of the ingredients is listed. 

Not applicable.

Trade name: Extra-Strength Cleaner

Product as SOLD 

Product at USE DILUTION

• Section 313 (Specific toxic chemical listings):

None of the ingredients is listed. 

None of the ingredients is listed.

• TSCA (Toxic Substances Control Act):

All ingredients are listed. 

All ingredients are listed.

• Chemicals known to cause cancer:

None of the ingredients is listed. 

None of the ingredients is listed.

• Chemicals known to cause reproductive toxicity for females:

None of the ingredients is listed. 

None of the ingredients is listed.

• Chemicals known to cause reproductive toxicity for males:

None of the ingredients is listed. 

None of the ingredients is listed.

• Chemicals known to cause developmental toxicity:

None of the ingredients is listed. 

None of the ingredients is listed.

• EPA (Environmental Protection Agency)

None of the ingredients is listed. 

None of the ingredients is listed.

• IARC (International Agency for Research on Cancer)

112926-00-8 

Precipitated silica (Silica-Amorphous) 

3 

Not applicable.

• TLV (Threshold Limit Value established by ACGIH)

None of the ingredients is listed. 

None of the ingredients is listed.

• NIOSH-Ca (National Institute for Occupational Safety and Health)

None of the ingredients is listed. 

None of the ingredients is listed.

• OSHA-Ca (Occupational Safety & Health Administration)

All ingredients are listed. 

All ingredients are listed.

• Canadian Domestic Substances List (DSL)

All ingredients are listed. 

All ingredients are listed.

• Canadian Ingredient Disclosure list (limit 0.1%)

None of the ingredients is listed. 

None of the ingredients is listed.

• Canadian Ingredient Disclosure list (limit 1%)

25155-30-0 

sodium dodecylbenzenesulphonate 

Not applicable.

497-19-8 

Sodium Carbonate 

Not applicable.

Trade name: Extra-Strength Cleaner

16 Other information